D-902

Establishment of Specifications

Section D — Laboratory Operations and Specifications Revision 1 20 pages

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1.0 Purpose 
 
 The purpose of this procedure is to provide guidelines for the establishment of specifications to
 control the identity, strength, composition, and purity of products manufactured by Ion Labs,
 
 Inc. 
 
 2.0 Scope 
 
 This procedure is applicable in establishing specifications for the release of components and
 
 raw materials used to manufacture food products, cosmetic products, dietary supplements, and
 drug products. It is also applicable to the establishment of stability and release specifications
 
 for these products. While this SOP provides guidance for establishing specifications,
 additional considerations may be required for each individual component, raw material, or
 
 product to reasonably ensure the identity, strength, composition, and purity of finished products
 
 manufactured by Ion Labs, Inc. 
 
 3.0 Responsibility 
 
 3.1 It is the responsibility of the QC Lab, R&D and Analytical Development to establish
 
 appropriate specifications for raw materials and manufactured products to control the
 identity, strength, composition and purity of products manufactured by Ion Labs.
 
 4.0 Definitions 
 
 4.1 TAMC -— Total Aerobic Microbial Count 
 
 4.2 TYMC — Total Combined Yeast/Molds Count 
 
 4.3. Drug - The Federal Food, Drug, and Cosmetic Act (FD&C Act) and FDA regulations
 
 
 

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 define the term drug as: 
 
 4.3.1 A substance recognized by an official pharmacopoeia or formulary.
 
 4.3.2 A substance intended for use in the diagnosis, cure, mitigation, treatment, or
 prevention of disease. 
 
 4.3.3 A substance (other than food) intended to affect the structure or any function of
 the body. 
 
 4.3.4 A substance intended for use as a component of a medicine but not a device or a
 
 component, part or accessory of a device. 
 
 4.3.5 Biological products are included within this definition and are generally covered
 
 by the same laws and regulations, but differences exist regarding their
 manufacturing processes (chemical process versus biological process.)
 
 4.4 Dietary Supplement - Congress defined the term "dietary supplement" in the Dietary
 Supplement Health and Education Act of 1994 (DHSEA). A dietary supplement is a
 
 product taken by mouth that contains a "dietary ingredient" intended to supplement the
 diet. Dietary supplements can also be extracts or concentrates, and may be found in
 
 many forms such as tablets, capsules, softgels, gelcaps, liquids, or powders. They can
 
 also be in other forms, such as a bar, but if they are, information on their label must not
 represent the product as a conventional food or a sole item of a meal or diet. Whatever
 
 their form may be, DSHEA places dietary supplements in a special category under the
 general umbrella of "foods," not drugs, and requires that every supplement be labeled a
 
 dietary supplement. Unlike drugs, supplements are not intended to treat, diagnose,
 
 prevent, or cure diseases. That means supplements should not make claims, such as
 “reduces pain” or “treats heart disease.” Claims like these can only legitimately be
 
 made for drugs, not dietary supplements. 
 
 4.5 Dietary Ingredient / New Dietary Ingredient - DHSEA defined both of the terms
 
 "dietary ingredient" and "new dietary ingredient" as components of dietary
 supplements. In order for an ingredient of a dietary supplement to be a "dietary
 
 ingredient," it must be one or any combination of the following substances:
 
 

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 4.5.1 avitamin 
 
 4.5.2 amineral 
 
 4.5.3 an herb or other botanical 
 
 4.5.4 anamino acid 
 
 4.5.5 adietary substance for use by man to supplement the diet by increasing the total
 dietary intake 
 
 4.5.6 aconcentrate, metabolite, constituent, or extract 
 
 4.5.7 A "new dietary ingredient" is one that meets the above definition for a "dietary
 
 ingredient" and was not sold in the U.S. before October 15, 1994.
 
 4.6 Color Additive - A color additive is a dye, pigment or other substance, which is
 
 capable of imparting color when added or applied to a food, drug, cosmetic, or to the
 
 human body. The legal definition can be found in Section 201(t) of the FD&C Act and
 provides exclusions as well. Color additives for use in food, drugs, and cosmetics
 
 require premarket approval. 
 
 4.7 Colorant - A colorant is a dye, pigment, or other substance that is used to impart color
 
 to or to alter the color of a food-contact material, but that does not migrate to food in
 amounts that will contribute to that food any color apparent to the naked eye. The term
 
 ‘colorant’ includes substances such as optical brighteners and fluorescent whiteners,
 
 which may not themselves be colored, but whose use is intended to affect the color of a
 food-contact material. (21 CFR 178.3297(a)). 
 
 4.8 Food Additive - A food additive is defined in Section 201(s) of the FD&C Act as any
 substance that may reasonably be expected to become a component of or otherwise
 
 affect the characteristic of any food (including any substance intended for use in
 producing, manufacturing, packing, processing, preparing, treating, packaging,
 
 transporting, or holding food; and including any source of radiation intended for any
 
 such use). 
 
 

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 49 GRAS - "GRAS" is an acronym for the phrase Generally Recognized As Safe. Under
 sections 201(s) and 409 of the FD&C Act, any substance that is intentionally added to
 
 food is a food additive, that is subject to premarket review and approval by FDA, unless
 the substance is generally recognized, among qualified experts, as having been
 
 adequately shown to be safe under the conditions of its intended use, or unless the use
 
 of the substance is otherwise exempted from the definition of a food additive. GRAS
 substances are distinguished from food additives by the type of information that
 
 supports the GRAS conclusion, that it is publicly available and generally accepted by
 the scientific community, but should be the same quantity and quality of information
 
 that would support the safety of a food additive. Additional information on GRAS can
 
 be found on the GRAS Notification Program page. 
 
 410 Indirect Food Additive - In general, these are food additives that come into contact
 
 with food as part of packaging, holding, or processing, but are not intended to be added
 directly to, become a component, or have a technical effect in or on the food. Indirect
 
 food additives mentioned in Title 21 of the U.S. Code of Federal Regulations (21CFR)
 used in food-contact articles, include adhesives and components of coatings (Part 175),
 
 paper and paperboard components (Part 176), polymers (Part 177), and adjuvants and
 
 production aids (Part 178). Currently, additional indirect food additives are authorized
 through the food contact notification program. In addition, indirect food additives may
 
 be authorized through 21 CFR 170.39. 
 
 4.11 Secondary Direct Food Additive - This term is in the title of 21 CFR 173, which was
 
 created during recodification of the food additive regulations in 1977. A secondary
 direct food additive has a technical effect in food during processing but not in the
 
 finished food (e.g., processing aid). Some secondary direct food additives also meet the
 
 definition of a food contact substance. For more on food contact substances, consult the
 Food Contact Substance Notification Program. 
 
 4.12 Cosmetic - The Federal Food, Drug & Cosmetic Act (FD&C Act) defines cosmetics as
 "articles intended to be rubbed, poured, sprinkled, sprayed on, introduced into, or
 
 otherwise applied to the human body...for cleansing, beautifying, promoting
 attractiveness, or altering the appearance." Included in this definition are products such
 
 

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 as skin moisturizers, perfumes, lipsticks, fingernail polishes, eye and facial makeup
 preparations, shampoos, permanent waves, hair colors, toothpastes, and deodorants, as
 
 well as any material intended for use as a component of a cosmetic product. The FD&C
 Act prohibits the sale of “any food, drug, device, or cosmetic that is adulterated or
 
 misbranded” [section 301(a); 21 U.S.Code 331(a)]. Furthermore, a cosmetic shall be
 
 deemed to be adulterated “if it bears or contains any poisonous or deleterious substance
 which may render it injurious to users under the conditions of use prescribed in the
 
 labeling thereof.” While the law does not require cosmetics to have FDA approval
 before they go on the market, the FDA does monitor the safety of cosmetics, including
 
 their microbiological safety, and FDA can take action against cosmetics on the market
 
 that don’t comply with the law (Microbiological Safety and Cosmetics, www.fda.gov).
 
 Note: Some products qualify both as cosmetics and as OTC drugs. This may happen
 
 when a product has two intended uses, with ingredients intended to do two
 different things. For instance, a shampoo is a cosmetic, since its intended use is
 
 to cleanse the hair. An anti-dandruff treatment is a drug, because its intended use
 is to treat dandruff. Consequently, an anti-dandruff shampoo is both a cosmetic
 
 and a drug. Among other cosmetic/drug combinations are toothpastes that
 
 contain fluoride, deodorants that are also anti-perspirants, and moisturizers and
 makeup marketed with sun-protection claims. 
 
 4.13 Food - Food is any substance that is usually composed of carbohydrates, fats, proteins
 and water. It can be eaten or drunk by any animal including humans for nutrition or
 
 pleasure. Most of the foods are of plant or animal origin. 
 
 4.14 IAV - Ingredient Addition Verification (IAV) is the process of verifying that the
 
 required amount of an indicated ingredient has been added to the batch and calculating
 
 the resulting amount that would be in a final unit of product. This approach of strength
 assessment for a unit dose is necessary when it is not possible to test for a component in
 
 the final product. Emphasis is on verification of the quality of the incoming raw
 material. 
 
 5.0 References 
 
 

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 5.1 21 CFR 110 Current Good Manufacturing Practice in Manufacturing, Packaging, or
 Holding Human Food. 
 
 5.2 21 CFR 111 Current Good Manufacturing Practice in Manufacturing, Packaging,
 Labeling, or Holding Operations for Dietary Supplements. 
 
 5.3 21 CFR 210 Current Good Manufacturing Practice in Manufacturing, Processing,
 
 Packaging, or Holding of Drugs; General 
 
 5.4 21 CFR 211 Current Good Manufacturing Practice for Finished Pharmaceuticals
 
 5.5 21 U.S. Code Sections 321-399i — Federal Food, Drug, and Cosmetic Act
 
 5.6 U.S. Department of Health and Human Services, National Institutes of Health, Office of
 
 Dietary Supplements, Dietary Supplement Health and Education Act of 1994.
 
 5.7 USP <1112> Application of Water Activity Determination to Nonsterile
 
 Pharmaceutical Products. 
 
 5.8 USP < 232> Elemental Impurities — Limits 
 
 5.9 USP <2023> Microbiological Attributes of Nonsterile Nutritional and Dietary
 Supplements 
 
 5.10 USP <2232> Elemental Contaminants in Dietary Supplements 
 
5.11 Bacteriological Analytical Manual, 8th Edition, Revision A, 1998. Chapter 23

 5.12 California Proposition 65 (Prop 65) — Safe Drinking Water and Toxic enforcement Act
 
 of 1986 
 
 5.13 Food Safety Modernization Act (FSMA) 
 
 6.0 Establishment of Specification Steps 
 
 The establishment of specifications is dependent upon multiple factors. Those factors
6.1 are discussed here and are presented as a flow chart in the next section.

 

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 6.1.1 FDA CFR Requirements 
 
 FDA CFR 111 defines the basic testing requirements for each
 
 component that is used in the manufacture of a dietary supplement
 along with the testing requirements for a Finished Batch. These
 
 requirements include establishing specifications to ensure Identity,
 
 Purity, Strength, and Composition. In addition, limits on those types
 of contaminates that may adulterate or may lead to adulteration of the
 
 finished batch of the dietary supplement to ensure the quality of the
 dietary supplement must be established. 
 
 6.1.2 Use Class 
 
 The determination of appropriate test specifications for a raw material
 
 or product is dependent upon the “Use Class” of the product or
 
 material. For finished products, the class of the product is determined
 based on the definitions provided in this SOP. For raw materials, the
 
 use class is determined based on the product the raw material will be
 used in. 
 
 For raw materials that are used in products with different use classes,
 the most restrictive class should be used. Alternatively, multiple ID
 
 numbers may be created for a multi-class raw material such that
 
 different specifications may be established depending upon the use.
 
 6.1.3 Label Claims and Special Declarations 
 
 Additional specifications may be required based on label claims.
 Strength/Assay tests are required for components identified and
 
 quantitated on a label claim. Additionally, if a product label declares
 the product to be Organic, or Kosher, then restrictions or testing may
 
 need to be added to ensure that the product meets these claims. If the
 product claims to be USP, the USP monographs should be used to
 
 establish specifications. 
 
 

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 6.1.4 Manufacturing Considerations 
 
 Certain specifications for raw materials may also be considered for
 
 product/ process functional requirements. For example, particle size,
 moisture levels, and density may all have an impact on production of a
 
 finished good. These requirements should be established when a New
 
 Product Assessment is completed. 
 
 6.1.5 Specific Regulations 
 
 Specific regulations are in place for some products and materials. For
 example, there are specific regulations associated with certain foods,
 
 dyes, etc. Additionally, if a product is manufactured to be distributed
 outside the USA, then regulations associated with that destination must
 
 be considered. 
 
 6.1.6 Customer Requirements 
 
 Customer requirements must also be considered. Specifications should
 
 ensure that the product manufactured will meet both the customer and
 regulatory expectations. 
 
 6.1.7 Summation of Considerations 
 
 The final specification is based on the summation of all of the
 
 considerations outlined above. If this process identifies conflicting
 testing or specification limits, then the most restrictive testing and
 
 limits should be chosen. 
 
 

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 6.2 Establishment of Specification Flow Chart 
 
 < Start :) RMDtheatte Ursmien Cel atshse tUos teh Cel RasMs. o fI ftthhee FRinMi sihs euds Perdo dinu cmtu(lst)i p(lFeP) prtohdeu cRtMsi wsi uths eddi fifne raenndt aUpspel y ——
 
 Classes, the most restrictive class should be used. Alternatively create multiple RM
 item numbers so that each RMis used in only one product Use Class.
 
 Determine Finished Product (FP)Use Cl 
 Determine the Use Class of the Finished Product (FP). The UseClassis based on both,
 Pele vce RM or FP FP—»} what isin the product, and what the product claimsto do. Use the definitions ofeach /¢—
 Use Class 
 Use Class to properly classify the product. For Raw Materials, this step applies to the
 FP the RMis used in. 
 RM /FP Class NOTE: Pet products are 
 classified as either a Food
 or aDrug. Thereis no 
 emecceaseeseseneae 
 classification for Pet 
 Food Cosmetic pletely Drug d+ 
 Supplements 
 Supplement 
 v 
 Evaluate Label E Xampielses i| nclu‘de, but are not limited to: 
 vV 
 Evaluate Label Claims for special requirements that may apply to the given Use Class.
 Clai USP, Organic, Kosher, Distribution (i.e. do regulations other than US apply).
 aims Consider these restrictions as sourcing and testing requirements are determined and
 as subsequent steps in the process are executed.. 
 Apply “Certification” Search for FDA If international
 Evaluat If USP is claimed, P immita ‘dans guidance documents distribution is
 R aba . > use USP > (Organic, Kosher > or regulations -» applicable, search
 — monographs 6 Ete ; specific to the applicable 
 material or product regulations 
 Evaluate 
 Specific 
 Customer 
 Requirments End 
 L 
 ‘ 
 Build _| Apply lon Defaults _ Add more restrictive requirements discovered
 Specification "| based on Use Class during the “Evaluation” process above.
 
 

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 6.3 Identification Tests 
 
 6.3.1 Identification testing is required for all raw materials regardless of the Use
 Class. Identification testing should optimally be able to discriminate between
 materials of closely related structure and/or species that are likely to be present.
 Identification testing may require more than one test to provide assurance of
 
 specific identification. 
 
 6.3.2 The following table lists preferred identification techniques based on material
 type. This is not an all-inclusive list. Any suitable method for identification
 may be selected. 
 
 Material Type Preferred Test Comment 
 FTIR, Compendial, HPLC, or [700 ee 
 Pure Materials 
 Raman . ee 
 Oils related to specific sources, i.e.
 Pure oils and oil 
 USP Fatty Acid Composition coconut, olive, sunflower, will present a
 mixtures 
 unique fatty acid profile. 
 Reference material for some botanical
 TLC, Compendial, or HPLC 
 species may be unavailable in the 
 Botanicals component profile. Raman 
 marketplace. Reference section 6.3.4
 Spectroscopy if acceptable. 
 for further discussion. 
 Botanical blends may be identified 
 using specific markers that are present
 TLC or HPLC component profile. in blend, in combination with other
 Botanical Blends 
 Raman if acceptable. identification measures. Identification
 testing may be limited for botanical
 blends (see section 6.3) 
 Reference materials for flavors and
 colorants are typically not available. In
 Organoleptic, Density, Refractive 
 Flavors/ Colorants this case the physical characteristics of
 Index 
 the material will be used for 
 identification. 
 Pure material identified with 
 Pure materials presented on carriers.
 Triturates/ Pure strength evaluation. 
 Both the pure material and carrier
 material blends FTIR or USP wet chemistry for 
 should be confirmed if possible. 
 carrier identification. 
 6.3.3 Identification by Chromatographic Retention Time and Spectral Match
 1. Identification by a single chromatographic retention time may be used
 for both components and finished batches. For components, the use of
 

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 Establishment of Specifications 
 
 both retention time and/ or spectral match may be used as the sole
 source of identification. Typical acceptable range for spectral match is
 > 900. Spectral matching for individual components on finished
 batches may be difficult as the finished batch usually consists of
 
 several components. 
 
 6.3.4 Identification by Spectroscopy 
 
 iF Spectroscopy techniques for identification (i.e. FTIR, or Raman) are
 good sources of identification for pure materials; however, may not be
 adequate for botanicals, blends and mixtures. For example, the unique
 
 component(s) of many botanical ingredients are present in low
 concentration, and as a result, the botanical may not be uniquely
 identifiable by spectroscopic means. In some cases, it may be possible
 to subtract the background spectrum and generate a spectrum that is
 unique to the blend. However, in general, caution should be taken
 
 when using Spectroscopy for identification of blends and mixtures.
 
 6.3.5 Reference Materials for Identification 
 
 1. Qualified reference materials should used to establish the identity of all
 components and finished batches. Qualified reference materials
 include compendial standards, in-house qualified or commercially
 
 available secondary standards (typically qualified against compendial
 standards), and botanical reference materials. Reference materials are
 typically accompanied by a C of A that has an established potency,
 expiration date, or genus/ species identification for botanicals.
 
 6.3.6 Identification Limitations 
 
 l. There are physical / chemical limitations to identification testing for
 some materials / products. For example, proprietary blends of
 ingredients may not uniquely identifiable by spectral or chemical
 analyses. For raw materials that are comprised of a blend of multiple
 components, identification may be carried out by marker testing. For
 
 example, a blend of multiple botanical ingredients may be identified
 using TLC for one or more of those ingredients. 
 
 For any component in which reference material is unavailable,
 organoleptic (taste, odor, color) in conjuction with any other physical
 characteristics (density, refractive index, pH) may be used to establish
 
 identity. 
 
 

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 6.4 Purity — Microbiological Tests 
 
 6.4.1 Microbiological Limits 
 
 l. Microbiological limits must be considered for all products and
 materials; however, microbiological testing is not required for all
 materials or all products. Physical factors of the material / product
 
 may greatly reduce the risk of microbiological contamination. For
 example, materials / products with low pH or low water activity may
 have a very low risk and may not require microbiological testing.
 
 By default, Ion Labs uses guidance from the USP and FDA to establish
 microbiological limits based on the material source and _ use.
 
 Specifically: 
 
 6.4.1.2.1 For the Drug Product use class — USP (1111) 
 Microbiological examination of nonsterile products:
 Acceptance criteria for pharmaceutical preparations and
 
 substances for pharmaceutical use 
 
 6.4.1.2.2 For Dietary Supplements — USP (2023) Microbiological
 attributes of nonsterile nutritional and dietary supplements
 
 6.4.1.2.3 For Cosmetics and Food, - Bacteriological Analytical
 Manual (BAM), 8th Edition, Revision A, 1998. Chapter 23
 
 6.4.2 Interpretation of USP Microbiological Limits 
 
 1. The USP acceptance criterion for microbiological quality as it pertains
 to quantitative analyses has an allowable variability of the final colony
 forming units (CFU). There is a two-fold tolerance in the final results.
 For example, if the monograph requires a 100 cfu/ml limit, the
 acceptable upper limit would be 200 cfu/ml. Additional information is
 
 included in the “Interpretation of the Results” section of USP <61>.
 
 When an acceptance criterion for microbiological quality is prescribed,
 it is interpreted as follows: 
 
 6.4.2.2.1 10! cfu: maximum acceptable count = 20; 
 
 6.4.2.2.2 10° cfu: maximum acceptable count = 200; 
 
 6.4.2.2.3 10° cfu: maximum acceptable count = 2000; 
 
 

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 Establishment of Specifications 
 
 6.4.2.2.4 and so forth. 
 
 Ion Labs specifications should factor this variability into our
 specification and list the specification with the two-fold tolerance
 already included. 
 
 6.4.3. Water Activity and Microbiological Reduced Testing 
 
 l. Low water activity (aw) in a material or product will greatly assist in
 the prevention of microbial proliferation. Because the water activity
 requirements for different Gram-reactive bacteria, bacterial spores,
 yeasts, and molds are well described in literature, the appropriate
 microbial limit testing program for products of differing water
 
 activities can be established. Reduced microbial limits testing may be
 justified through risk assessment. This reduction in testing, when
 justified, may entail forgoing full microbial limits _ testing,
 implementing skip-lot testing, or eliminating routine testing. Table 1 in
 
 USP <1112> provides a list of “Water Activity (aw) required to
 Support the Growth of Representative Microorganisms.” 
 
 Water activities below or equal to 0.60 are less than the required aw for
 every microorganism in USP <1112> Table 1. As such, if aw for a
 material or product is < 0.60, then reduced testing may be considered.
 
 6.5 Purity - Heavy Metals 
 
 6.5.1 There are specific requirements for metals content based on the product Use
 Class as follows: 
 
 1. Drug Products — USP <232> 
 
 2. Dietary Supplements — USP <2232> 
 
 3. Food / Cosmetics — No general requirements, but there may be specific
 
 requirements for specific items (i.e. water, fish, etc.)
 
 6.5.2 In addition, specific requirements for heavy metals should be considered for
 variable markets, i.e. Prop 65 (California) and Canada. 
 
 6.5.3 Although evaluation of heavy metals may not be required for certain product
 classifications, any raw material or finished good may be evaluated for heavy
 metals as deemed necessary. For Dietary Supplements, the four elements
 defined in Prop 65, lead, arsenic, cadmium, and mercury, will be the default
 
 elements for testing. 
 
 

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 6.6 Strength / Assay 
 
 6.6.1 Strength/Assay testing of raw material components provides valuable
 information as to the suitability of that raw material for use in drug product. For
 raw materials used in dietary supplements, strength testing is generally
 performed on the first three lots of a new raw material, and once annually
 
 thereafter. For finished goods strength testing is typically evaluated if the
 component is part of a label claim or requested by the client. Additional details
 are provided in Section 6.8. 
 
 6.7. Physical Characteristics / Composition 
 
 6.7.1 The physical characteristics of both raw materials and finished products are
 critical parameters as to the identification and correct composition of said
 materials. Physical characteristics and Composition testing include: FTIR,
 Appearance, Form, LOD (loss on drying), KF (Karl Fisher), pH, etc. Typically
 physical characteristics of a raw material or finished product, such as
 
 appearance, are evaluated on every lot. Composition testing such as LOD or KF
 are only determined on full test lots of raw materials. These tests may be
 removed during reduced testing evaluations. Additional details are provided in
 Section 6.8. 
 
 6.7.2 In addition, outside of normal release testing, Content Uniformity (CU) for any
 tablet or capsule may be performed to establish uniform composition of any
 
 product. CU testing is not a release requirement and will be a protocol driven
 evaluation. 
 
 6.8 Alert Limits 
 
 6.8.1 In place of a defined specification, some analytical testing may have an “alert”
 limit. These limits are in place only to alert appropriate departments of a potential
 
 impact from the observed result. These limits are not a pass/ fail.
 
 6.8.2 Some examples would be heavy metals, particle size or density evaluation of a raw
 material. Most raw material ID’s are used in multiple products, therefore, heavy
 metals, particle size or density requirements could potentially be different for each
 
 product. 
 6.8.3. When atest result observed exceeds an alert limit, the QC lab will initiate Form D-
 
 902-F1 Alert Limit Impact Assessment, and route to the appropriate personnel to
 conduct the impact assessment. 
 
 6.8.4 This impact assessment should include: 
 
 

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 1. An understanding of which product this material will be used. This
 information typically will be provided by purchasing. 
 
 2. What, if any, negative impact may occur from the use of this material.
 
 3. Approval for use signatures from all associated departments.
 
 6.8.5 The completed Impact Assessment will be archived with the raw material release
 
 packet if applicable. 
 
 6.9 Default Testing Based on Use Class 
 
 6.9.1 The tables provided in this section provide a summary of default testing based
 on the information provided in this SOP. These tables provide typical defaults
 for establishing specifications, but the final specification for each individual
 component, raw material, or product must reasonably ensure the identity,
 
 strength, composition, and purity of finished products manufactured by Ion
 Labs, Inc. 
 
 

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 Standard Operating Procedure SOP No | Rev eer 
 Establei shment of Specief icatie ons D-=1 02 a °e Oo 
 
 Drug 
 
 Table 1 — Drug Default Testing 
 RM Release |__RMCoA Challenge_ FP Release FP Stability 
 Identification USP? USP? Not required. 
 Same as RM CoA USP?. Also reference Same as Stability. USP’. Also reference
 Challenge. USP <1111> USP <1111> 
 After Challenge lots, if | Generally Generally 
 aw < 0.60 (see USP Nonaqueous Nonaqueous 
 <1112>) then only test preparations for oral preparations for oral
 aw use use 
 e TAMC NMT 2000 e TAMC NMT 2000 
 e TYMC NMT 200 e TYMC NMT 200 
 e Absence of e Absence of 
 Purity — E. coli in 10 g E. coli in 10 g 
 Microbiological! 
 Aqueous preparations Aqueous preparations 
 for oral use for oral use 
 e TAMC NMT 200 e TAMC NMT 200 
 e TYMC NMT 20 e TYMC NMT 20 
 e Absence of e Absence of 
 E. coli in 10 g E. coli in 10 g 
 Test aw — Report Value. 
 Based on results test 
 less at release. 
 Conduct a Risk Not Required 
 Assessment (RA) of the 
 24 elements listed in 
 ; ; ; USP <232>. Based on 
 Not Required unless Required unless Risk RA. determine if RM
 Purity — Risk ; Assessm o en s t Assessm ; ent must be monitored. If 
 Heavy Metals requires monit . oring Determines that RM are monit ; ored, FP
 for FP compliance control of RM is not 8 . 
 with USP <232> necessar testing is not requiredI.f 
 y RM are not monitored, 
 typically test one lot 
 per year (i.e. Stability 
 Lot). 
 Strength / Assay USP USP 
 Composition — A ; 
 Content Uniformity N/A N/A USP Not Required 
 Only include testing 
 ; Le form the RM CoA 
 Euyalcat COAERCIERISHES Challenge testing that USP? USP? 
 / Composition il 
 are likely to change 
 during shipment. 
 Note: ‘Limits placed in the Ion Labs specification for Microbiological purity are double the values
 listed in source references based on discussion in section 6.4. 
 2USP — as used here implies Full USP Monograph or other compendia source as available for
 the material or product. 
 

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 Dietary Supplement 
 Table 2 — Dietary Supplement Default Testing 
 RM Release RM CoA Challenge FP Release FP Stability 
 Use the most robust form of ID available. Typical 
 testing includes ; 
 e Organoleptic 
 e HPLC ; 
 Identification _ ; Not required. 
 e TLC — Botanical, Botanical Extracts ° Retention Time Match 
 e FTIR or Raman — Fine Chemicals, pure materials 
 e Organoleptic (Color, form, Odor) - Flavors 
 USP <2023> 
 Generally 
 ¢ TAMC NMT 2000 pe 
 TYMC NMT 200 walle 
 Same as RM CoA ° 
 Challenge. e Absence of ° TAMC NMT 200 
 Puri E. coli in 10 g e TYMC NMT 200 
 Miurcitry bi—ol ogical? After Challenge lots, | Botanicals Same as Stabilviyty. e Absence of
 if aw < 0.60 (see USP E. coli in 10 g 
 <1112>) then only e¢ USP <2023> see specific . 
 festa, definitions Botanicals 
 e USP <2023> see 
 Test aw — Report Value. specific definitions
 Based on results test less at 
 release. 
 USP <2232> USP <2232> 
 (ug/g) PDE (ug/day) 
 e As 8 AS 
 1.5 15 
 ° Cd ® Cd 
 HPueraivtyy —M etals Not Requi;r ed : 0.5 Pb ° 5 Pb Not Requi.red 
 0.5 5 
 @ Hg ® Hg 
 total total 
 @ Methyl Methyl HG 2 
 HG 0.2 
 Typically not es ton stren para ne Test each component that has a label claim. If not
 Strength / Assay Required component is the source of a possi ; ble to test, use IAV calculation on release
 label claim on the product. 
 As applicable and if
 needed to support 
 As applicable © Orpanolepile 
 ys evaluation 
 ¢ Organoleptic evaluation e Same as stability Dis; ,
 Physical — testing; however some | ® Visintegration or
 y i Typically not ¢ Bulk Density testing may be reduced Dissolution
 Characteristics / Required T d Densi based .; 
 Composition equire e Tapped Density ased on supporting e Bulk Density
 stability and/or 
 a pH e Tapped Density 
 historical release data. 
 e LOD e Hardness 
 e Friability 
 e pH 
 Note: !Limits placed in the Ion Labs specification for Microbiological purity are double the values
 listed in source references based on discussion in section 6.4. 
 

[SOP 

 Standard Operating Procedure SOP No | Rev Saintes 
 Establ°i shment of Speci"f icati. ons De 2 . age Oo 
 
 Cosmetic 
 
 Table 3 — Cosmetics Default Testing 
 RM Release | RM CoA Challenge_ FP Release FP Stability 
 Use at least one ID test. Typical ID testing: Use at least one ID test.
 ¢ FTIR or Raman > 0.90 compared to Product Blend Std | Typical ID testing:
 ; ‘ e FTIRorRaman > 
 Identification ¢ Organoleptic (Color, form, Odor) 0.90 compared to Not required.
 Product Blend Std 
 e Organoleptic 
 Generally”? 
 TAMC NMT 2000 . 
 TYMC NMT 200 score 
 @ 
 ib P e TAMC NMT 2000 
 e sence 0 
 Same as RM CoA pathogenic organisms ¢ TYMC NMT 200 
 Challenge. Used near Eyes?* e Absenceof 
 Purity — © TAMC NMT 1000 i pathogenic organisms
 Microbiological! After Challenge lots, if ay YMC aT 100 AUIS Bs STADE. Used near Eyes”?
 ® 
 Ww e sence 0 
 pathogenic organisms ¢ TYMC NMT 100 
 e Absence of 
 Test ay — Report Value. pathogenic organisms
 Based on results test less at 
 release. 
 Conduct a Risk 
 Assessment (RA) of 
 the elements listed in 
 USP <2232>. Based 
 Not Required unless Risk Required unless Risk on RA, determine if
 ‘ Assessment requires ; RM must be 
 Purity — ee Assessment Determines ; : 
 monitoring for FP ‘fat control oF RIM is not monitored. If RM are Not Required
 Heavy Metals compliance with USP neeese monitored, FP testing 
 <232> ary is not requiredI.fRM 
 are not monitored, 
 typically test one lot 
 per year (i.e. Stability 
 Lot). 
 Strength / Assay Not Required Not Required Not Required Not Required 
 Physical 
 Characteristics / Not Required Not Required pH pH 
 Composition 
 Note: ‘Limits placed in the Ion Labs specification for Microbiological purity are double the values
 listed in source references based on discussion in section 6.4. 
 Bacteriological Analytical Manual, 8th Edition, Revision A, 1998. Chapter 23
 For eye area products, it is recommended to decrease the limits listed here by one half.
 
 

[SOP 

 Standard Operating Procedure SOP No | Rev Pace 19 of 19 
 Establ®i shment of Speci°f icatia ons ts est l a : e€ 0 
 
 Food 
 
 Table 3 — Food Default Testing 
 RM CoA 
 RM Release Challenge FP Release FP Stability 
 Identification e Organoleptic (Color, form, Odor) Not Required Not required.
 Same as RM CoA Generally Same as Stability. Generally” 
 Challenge. ¢ TAMC NMT 2000 © TAMC NMT 2000 
 
 After Challenge lots, | © TYMC NMT 200 ¢ TYMC NMT 200 
 if ay < 0.60 (see USP | @ Absence of e Absence of 
 Purity — <1112>) then only pathogenic pathogenic 
 Microbiological! | test aw organisms organisms 
 
 Test ay — Report 
 Value. Based on 
 results test less at 
 release. 
 Hears Mien Not Required Not Required Not Required Not Required 
 
 Strength / Assay Not Required Not Required Not Required Not Required 
 Physical 
 Characteristics / Not Required Not Required Not Required Not Required 
 Composition 
 Note: 'Limits placed in the Ion Labs specification for Microbiological purity are double the values
 listed in source references based on discussion in section 6.4. 
 Bacteriological Analytical Manual, 8th Edition, Revision A, 1998. Chapter 23
 
 7.0 Revision History 

| Rev | Date | Description of Changes | CCR # | By |
|-----|----------|------------------------|-------|----|
| 0 | 06/26/19 | New N/A J. Sassman 07/16/21 Added section for alert limits. CC-21-0284 J. Sassman | - | - |

 

[SOP 

 Alert Li4mit Impact Assessment 
 
 Form* D-902-F 1 CCR No. N/A Revision 0 
 * 
 
 Material Information 
 
 Department Notification